Distinct magnetic dynamic behavior for two polymorphs of the same Dy(III) complex.
نویسندگان
چکیده
Two polymorphs of the same Dy(III) complex show distinct slow magnetic relaxation behaviors due to the different local environments of Dy(III) in the crystal. This work represents the first example where the magnetic dynamic property of neutral rare earth complexes could be tuned by growing polymorphic crystals without changing the ligand.
منابع مشابه
On the effect of grain size on rock behavior under cyclic loading by distinct element method
It is well-known that the mechanical behavior of rocks under cyclic loading is much different from static loading conditions. In most constructions, the load applied to structures is within dynamic ranges. That’s why a great deal of attention has been paid towards this field in order to identify the dynamic behavior of rocks in more details. Nevertheless, the nature of dynamic failure in rocks ...
متن کاملSolution state studies on thermodynamic parameters and complexation behavior of inner transition metal ions with creatinine in aqueous and mixed equilibria
The determination of formation constants of binary inner transition metal complexes where M=Y(III) or La(III) or Ce(III) or Pr(III) or Nd(III) or Sm (III) or Gd (III) or Dy (III) or Th(IV) andL = Creatinine have been carried out using Irving–Rossotti titration technique in aqueous mediaat different temperatures and at ionic strength. To understand more about the nature ofequilibrium involving i...
متن کاملStructural, magnetic and electrical properties of pure and Dy-doped Fe2O3 nanostructures synthesized using chemical thermal decomposition technique
Pure (S1) and Dy3+-doped α-Fe2O3 (S2 and S3) nanoparticles were prepared by a combustion synthesis method at 700 ºC for 8 h using Fe(acac)3 (Tris(acetylacetonato)Iron(III)) as raw material. Characterizations of the prepared powders were carried out by powder X-ray diffraction (PXRD). Structural analysis was performed b...
متن کاملA half-sandwich organometallic single-ion magnet with hexamethylbenzene coordinated to the Dy(III) ion.
A half-sandwich organolanthanide complex, [(C6Me6)Dy(AlCl4)3], in which Dy(III) is coordinated with a π-bonded arene was synthesized and magnetically characterized. This complex displays slow magnetic relaxation and a hysteresis loop associated with single-ion magnet behavior. The orientation of the magnetic anisotropy axis is analyzed using ab initio calculations.
متن کاملStructural, magnetic and electrical properties of pure and Dy-doped Fe2O3 nanostructures synthesized using chemical thermal decomposition technique
Pure (S1) and Dy3+-doped α-Fe2O3 (S2 and S3) nanoparticles were prepared by a combustion synthesis method at 700 ºC for 8 h using Fe(acac)3 (Tris(acetylacetonato)Iron(III)) as raw material. Characterizations of the prepared powders were carried out by powder X-ray diffraction (PXRD). Structural analysis was performed b...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 47 24 شماره
صفحات -
تاریخ انتشار 2011